Has there ever been a 9–5 in all competitions?

Yes, 2 times.

The first time: February 5, 1933, Athletic Bilbao beat Racing Santander (Athletic Bilbao 9–5 Racing Santander) · La Liga.

The last time: August 28, 1960, Feijenoord beat Ajax (Feijenoord 9–5 Ajax) · Eredivisie, 66 years ago.

Home wins: 2. Away wins: 0.

Nearby scores

1. 10–4 3 times
2. 10–5 Never
3. 10–6 Never
4. 9–4 2 times
5. 9–5 2 times
6. 9–6 Never
7. 8–4 8 times
8. 8–5 1 time
9. 8–6 Never

All games

1. August 28, 1960 Feijenoord 9–5 Ajax · Eredivisie
2. February 5, 1933 Athletic Bilbao 9–5 Racing Santander · La Liga