Has there ever been a 6–4 in the Ligue 1?

Yes, 7 times.

The first time: October 3, 1948, Stade de Reims beat SO Montpellier (Stade de Reims 6–4 SO Montpellier).

The last time: April 17, 1966, Red Star beat Lille OSC (Red Star 6–4 Lille OSC), 60 years ago.

Home wins: 6. Away wins: 1.

Nearby scores

1. 7–3 15 times
2. 7–4 1 time
3. 7–5 Never
4. 6–3 26 times
5. 6–4 7 times
6. 6–5 2 times
7. 5–3 69 times
8. 5–4 21 times
9. 5–5 2 times

All games

1. April 17, 1966 Red Star 6–4 Lille OSC
2. January 14, 1962 Stade Rennais 4–6 AS Monaco
3. May 1, 1960 Matra Racing 6–4 US Valenciennes-Anzin
4. October 11, 1959 Girondins de Bordeaux 6–4 FC Sochaux
5. August 18, 1957 Matra Racing 6–4 FC Sochaux
6. November 20, 1949 OGC Nice 6–4 Olympique de Marseille
7. October 3, 1948 Stade de Reims 6–4 SO Montpellier